Precise Lab Color

i'd like to recreate such color in ps. those values are measured by American Dental Association Laboratories and are precise, but the difference between samples is very low (L: 65,73 or 67,21)
1)how can i create such precise color is ps?
L:66,33
a:0,3
b:8,73

when i eyedropped my samples i had 16 bit values of the same sample like this:
L:26975
a:567
b:1339

2)why the difference is so huge?


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